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© Qualitech Chemical Corporation 2000

Rubber Chemicals
Product line
 
Antidegradants
Staining antioxidants with antiozonant effects

 Outstanding protection against dynamic stress, oxidation, heat, ozone and rubber poisons; these  antioxidants cause severe staining. For car, truck and earthmover tires, technical goods subjected to  dynamic stress, cable sheathing and insulation, inner tubes and roll covers.
 Qualinox 4020 is also used for stabilization in E-SBR production.

Product Chemical composition International abbreviation Density (g/cm3) Initial melting point (°C) Supply form
Qualinox® 4010 NA N-isopropyl-N'- phenyl-p-phenylenediamine IPPD 1.1 min. 76 6
Qualinox® 4020/LG N-(1,3-dimethylbutyl)-N'- phenyl-p-phenylenediamine 6PPD 1.0 min. 45 6
Qualinox® 4020 liquid solidification point min. 45 1
Qualinox® 4030 N,N'-bis-(1,4-dimethylpentyl)- p-phenylenediamine 77PD 0.9 - 1
Qualinox® 3100 mixture of diaryl-p-phenylene- diamines DTPD 1.2 min. 95 10
Qualinox® DPPD N,N'-diphenyl-p-phenylene- diamine DPPD 1.2 min. 135 10

Staining antioxidants without antiozonant effects

 Very good protection against oxidation and heat, and good protection from rubber poisons; staining  effects range from medium to relatively weak. Used in combination with p-phenylenediamines for heavily  stressed technical goods.

Product Chemical composition International abbreviation Density (g/cm3) Softening point (°C) Supply form
Qualinox® HS1 2,2,4-trimethyl-1,2-dihydroquinoline, polymerized TMQ 1.1 85-95 6

 1) This product is marketed by Bayer International SA, CH-1701 Fribourg, Switzerland


Non-staining antioxidants

 Protection against oxygen, heat and unorientated crack formation (crazing). To some extent effective  against fatigue and poisoning by heavy metals. Staining absent or minimal. No contact staining. For  white, light-colored or transparent goods, e.g. dipped articles, fabric proofings, technical rubber and
 latex goods.
 Qualinox BHT suitable for rubber goods produced by the solution dipping process.
 Qualinox MB, Qualinox MB 2 and Qualinox ZMB 2 used mainly for heat-resistant thiuram-cured goods.  Synergists with other antioxidants.

Product Chemical composition International abbreviation Density (g/cm3) Initial melting point (°C) Supply form
Qualinox® DS mixture of alkyl and aralkyl-substituted phenols - 0.9 - 1
Qualinox® DS/F mixture of alkyl and aralkyl-substituted phenols, solidified with inorganic filler - 1.3 - 2
Qualinox® SP mixture of styrenated phenols SPH 1.1 - 1
Qualinox® BKF 1 2,2'-methylene-bis- (4-methyl-6-tert.-butylphenol) BPH 1.0 min. 124 2
Qualinox® SKF 2 sterically hindered polynuclear phenol - 1.1 min. 105 2
Qualinox® ZKF 1 2,2'-methylene-bis- (4-methyl-6-cyclohexylphenol) - 1.1 min. 125 2
Qualinox® BHT 1 2,6-di-tert-butyl-4-methylphenol BHT 1.0 solidification point approx. 69 11
Qualinox® MB 2-mercaptobenzimidazole MBI 1.4 approx. 290, with decomposition 7
Qualinox® MB 2 4- and 5-methyl-2-mercaptobenzimidazole MMBI 1.3 approx. 290, with decomposition 7, 8
Qualinox® ZMB 2 zinc-4- and -5-methyl-2- mercaptobenzimidazole ZMMBI 1.5 approx. 300, with decomposition 3

 1) This product is marketed by the Basic and Fine Chemicals Business Group, Bayer AG
 2) This product is marketed by Bayer International SA, CH-1701 Fribourg, Switzerland


Non-staining antiozonants

Antiozonants for light-colored and black-containing Qualinizates which must not stain through contact.

Product Chemical composition International abbreviation Density (g/cm3) Initial melting point (°C) Supply form
Qualizon® AFS cyclic acetal - 1.1 min. 85 6
Qualizon® AFD enol ether - 1.0 - 1